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Afalon®

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

Telephone (02)9431 7800 (office hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: Linuron is a urea derivative. 
Trade Name: Afalon Herbicide
Product Use: Agricultural herbicide for use as described on the product label. 
Creation Date: February, 2008
This version issued: July, 2016 and is valid for 5 years from this date.
Poisons Information Centre: Phone 13 1126 from anywhere in Australia.

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: T, Toxic. N, Dangerous to the environment. Hazardous according to the criteria of SWA.

Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS.

SUSMP Classification: None allocated.

IMDG Classification: Class 9: Miscellaneous dangerous goods.

UN Number: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

GHS Signal word: DANGER

Acute Toxicity Oral Category 4
Carcinogenicity Category 2
Reproductive Toxicity Category 1
Specific Target Organ toxicity - repeated exposure Category 2
Hazardous to aquatic environment Short term/Chronic Category 1

HAZARD STATEMENT:
H302: Harmful if swallowed.
H351: Suspected of causing cancer.
H360: May damage fertility or the unborn child.
H373: May cause damage to organs through prolonged or repeated exposure.
H410: Very toxic to aquatic life with long lasting effects.

PREVENTION
P102: Keep out of reach of children.
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe fumes, mists, vapours or spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P281: Use personal protective equipment as required.

RESPONSE
P352: Wash with plenty of soap and water.
P301+P312: IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.                                                                                        P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P308+P313: If exposed or concerned: Get medical advice.
P391: Collect spillage.
P370+P378: Not combustible. Use extinguishing media suited to burning materials.

STORAGE
P405: Store locked up.
P410: Protect from sunlight.
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.

DISPOSAL
P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour: Brownish coloured liquid.
 

Odour: Aromatic odour.

Major Health Hazards: Linuron is harmful by ingestion, with reported oral LD50 values of 1200 to 1500 mg/kg in rats, and 2250 mg/kg in rabbits. The reported dermal LD50 in rabbits is greater than 5000 mg/kg. It has been reported to be a skin sensitizer in guinea pigs, and an eye irritant in rabbits, but not a skin irritant in rabbits. The 4-hour inhalation LC50 is 6.15 mg/L, which indicates slight toxicity by this route. 

 

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,%  TWA (mg/m3) STEL (mg/m3)
Linuron 330-55-2 36-40 not set not set
Other non hazardous ingredients secret to 100 not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed.Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Try to contain spills, minimise spillage entering drains or water courses.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is full fire kit and breathing apparatus.

Flash point:  Does not burn.
Upper Flammability Limit:  Does not burn.
Lower Flammability Limit:  Does not burn.
Autoignition temperature:   Not applicable - does not burn.
Flammability Class:   Does not burn.
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective glasses and, preferably, goggles. Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry. 

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.Storage: Although this is classed as a Dangerous Good, you may not need a license to store it. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label. 

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits  TWA (mg/m3) STEL (mg/m3)

 

Exposure limits have not been established by SWA for any of the significant ingredients in this product.

The ADI for Linuron is set at 0.01mg/kg/day. The corresponding NOEL is set at 1.25mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, June 2014.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that vapours and mists are minimised.

Eye Protection: Eye protection is not normally necessary when this product is being used. However, if in doubt, wear suitable protective glasses or goggles.

Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when skin contact is likely.

Protective Material Types: We suggest that protective clothing be made from the following: rubber, PVC.

Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. Safety deluge showers should, if practical, be provided near to where this product is being used. 

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Brownish coloured liquid.
Odour:  Aromatic odour
Boiling Point: Approximately 100°C at 100kPa.
Freezing/Melting Point: Approximately 0°C.
Volatiles:  Water component. 
Vapour Pressure:  2.37 kPa at 20°C (water vapour pressure). 
Vapour Density:  No data.
Specific Gravity: 1.17-1.21 at 20°C
Water Solubility:  Emulsifiable.
pH: 7.0 to 9.5
Volatility:  No data.
Odour Threshold:  No data.
Evaporation Rate: No data.
Coeff Oil/water distribution:  Linuron 3.07 (log P octanol/water)
Autoignition temp: Not applicable - does not burn.

 

section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.Incompatibilities: strong acids, strong bases, strong oxidising agents.Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.Polymerisation: This product will not undergo polymerisation reactions. 

section 11 - Toxicological Information: 

Toxicity: Acute toxicity: Linuron is of slight toxicity by ingestion, with reported oral LD50 values of 1200 to 1500 mg/kg in rats, and 2250 mg/kg in rabbits. The reported dermal LD50 in rabbits is greater than 5000 mg/kg. It has been reported to be a skin sensitizer in guinea pigs, and an eye irritant in rabbits, but not a skin irritant in rabbits. The 4- hour inhalation LC50 is 6.15 mg/L, which indicates slight toxicity by this route.Chronic toxicity: Skin sensitization was seen in guinea pigs repeatedly exposed. Alterations in red blood cells were seen in rats given 2.75 mg/kg/day over 2 years. Anaemia was seen in dogs at doses above 6.25 mg/kg/day.Reproductive effects: In a three-generation study, no reproductive effects were observed at doses of 12.5 mg/kg/day. These data suggest that reproductive effects are unlikely in humans at expected exposure levels.Teratogenic effects: Pregnant rabbits fed high doses of Linuron during the sensitive period of pregnancy had normal offspring at doses of up to 25 mg/kg/day, even though maternal weight gain was reduced. In rats, doses of 6.25 mg/kg/day did not produce teratogenic effects. These data suggest that Linuron is not likely to cause birth defects.Mutagenic effects: Linuron caused mutations in one microbial assay. But in several other mutagenicity and genotoxicity assays, including the Ames assay, E. coli culture assay, Chinese hamster ovary cell culture assay, and whole animal studies, Linuron showed no mutagenic or genotoxic activity. Thus, it appears that Linuron is either nonmutagenic or slightly mutagenic.Carcinogenic effects: Several animal studies of mice, rats, and dogs have shown that it produces non-malignant liver and testicular tumours. In these studies, doses of 72.5 mg/kg/day in rats caused testicular adenomas and 180 mg/kg/day in mice caused hepatocellular adenoma. These data are not sufficient to determine Linuron's carcinogenicity to humans.Organ toxicity: Rats and dogs fed Linuron for 2 years had detectable residues of Linuron in their blood, fat, kidney, and spleen, but these did not seem to be associated with adverse effects.Fate in humans and animals: In rats, Linuron breaks down completely after passing through the liver. It is thus unlikely to bioaccumulate in mammalian systems. Linuron is a SWA Class 3 Reproductive risk, possible risk of impaired fertility.This product is likely to cause decreased fertility in humans.Classification of Hazardous IngredientsIngredient                                                                       Risk PhrasesLinuron                                                                           Conc>=25%: T; R61; R40; R62; R22; R48/22Reproductive toxicity - category 1BCarcinogenicity - category 2Acute toxicity - category 4Specific target organ toxicity (repeated exposure) - category 2Hazardous to the aquatic environment (acute) - category 1Hazardous to the aquatic environment (chronic) - category 1Potential Health EffectsSee section 11 for Chronic exposure studies.Inhalation:Short term exposure: Available data indicates that this product is not harmful. However product may be mildlyirritating, although unlikely to cause anything more than mild transient discomfort.Skin Contact:Short term exposure: Available data indicates that this product is not harmful. It should present no hazards innormal use. However product may be mildly irritating, but is unlikely to cause anything more than mild discomfortwhich should disappear once contact ceases.Eye Contact:Short term exposure: This product may be mildly irritating to eyes, but is unlikely to cause anything more thanmild discomfort which should disappear once product is removed.Ingestion:Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this productis harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but isunlikely to cause anything more than transient discomfort.Carcinogen Status:SWA: Linuron is classified by SWA as a Class 3 Carcinogen, possibly carcinogenic to humans.See the SWA website for further details. A web address has not been provided as addresses frequently change.NTP: No significant ingredient is classified as carcinogenic by NTP.IARC: No significant ingredient is classified as carcinogenic by IARC.

section 12 - Ecological Information: 

Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.Effects on birds: Linuron is slightly toxic to birds; the reported 5- to 8-day dietary LC50 values are greater than 5000 ppm in Japanese quail, 3000 ppm in mallard ducks, and 3500 ppm in pheasants.Effects on aquatic organisms: Linuron is slightly toxic to fish and aquatic invertebrate species. The reported LC50 for Linuron in trout and bluegill is 16 mg/L. The median threshold levels, i.e. levels at which adverse, sub lethal effects were apparent in 50% of the test animals, are greater than 40 mg/L in crawfish and tadpoles exposed over a 48-hour period.Effects on other organisms: Linuron is nontoxic to bees.Environmental Fate:Breakdown in soil and groundwater: Linuron is moderately persistent in soils, with a field half-life of 30 to 150 days in various soils and under various conditions. A representative field half-life is estimated to be approximately 60 days. Microbial degradation is the major process by which Linuron is lost from soils; photodegradation and volatilization are not important contributors to its breakdown. The metabolites of Linuron (3,4-dichloroaniline and carbon dioxide) are less toxic than Linuron. Linuron is moderately bound to soil, and is soluble in water. Losses may occur through transport of Linuron in runoff water and on suspended colloidal matter. Linuron has been found at very low concentrations in well and groundwater samples in some US states.Breakdown in water: Linuron is slightly to moderately soluble in water, and is not readily broken down in water.Breakdown in vegetation: Linuron is more readily absorbed by roots from soil application, than by leaves from foliar application. The rate at which it is absorbed, translocated, and subsequently broken down (or metabolized) differs with various plant species. 

section 13 - Disposal Considerations: 

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.

section 14 - Transport Information: 

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L) or less; or IBCs, but classed as Dangerous by IATA and IMDG/IMSBC when carried by Air or Sea transport (see details below).UN Number: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.Hazchem Code: •3ZSpecial Provisions: 179, 274, AU01Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.Dangerous Goods Class: Class 9: Miscellaneous Dangerous Goods.Packing Group: IIIPacking Instructions: P001, IBC03, LP01Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight container with Dangerous Goods of Class 1 (Explosives). 

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.

section 16 - Other Information: 

This SDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
SWA Safe Work Australia, formerly ASCC and NOHSC
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.


Please read all labels carefully before using product.
This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice” (December 2011)
Copyright © Kilford & Kilford Pty Ltd, July, 2016.
http://www.kilford.com.au/ Phone (02)9251 4532