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Aphidex®

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Pirimicarb is a carbamate derivative.

Trade Name: 

Aphidex WG Aphicide

Product Use: 

Agricultural aphicide for use as described on the product label.

Creation Date: 

November, 2006

This version issued:

July, 2016

Poisons Information Centre:

Phone 13 1126 from anywhere in Australia.

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: T, Toxic. Hazardous according to the criteria of SWA.

Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.

SUSMP Classification: S6

ADG Classification: Class 6.1: Toxic substances.

UN Number: 2757, CARBAMATE PESTICIDE, SOLID, TOXIC

GHS Signal word: DANGER
Acute Toxicity Oral Category 3
Hazardous to aquatic environment Short term/Chronic Category 1

HAZARD STATEMENT:
H301: Toxic if swallowed.
H410: Very toxic to aquatic life with long lasting effects.

PREVENTION
P102: Keep out of reach of children.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves, protective clothing and eye or face protection.

RESPONSE
P352: Wash with plenty of soap and water.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTRE or doctor.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P391: Collect spillage.
P370+P378: Not combustible. Use extinguishing media suited to burning materials. Water fog or fine spray is
the preferred medium for large fires.

STORAGE
P405: Store locked up.
P410: Protect from sunlight.
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.

DISPOSAL
P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour: Off-white granulated solid.

Odour: No data.

Major Health Hazards: toxic if swallowed, harmful by inhalation and in contact with skin. Signs and symptoms associated with mild exposures to organophosphate and carbamate pesticides include: headache, fatigue, dizziness, loss of appetite with nausea, stomach cramps and diarrhoea; blurred vision associated with excessive tearing; contracted pupils of the eye; excessive sweating and salivation; slowed heartbeat, often fewer than 50 per minute; rippling of surface muscles just under the skin. These symptoms may be mistaken for those of flu, heat stroke or heat exhaustion, or upset stomach. Moderately severe organophosphate and carbamate insecticide poisoning cases exhibit all the signs and symptoms found in mild poisonings, but in addition, the victim: is unable to walk; often complains of chest discomfort and tightness; exhibits marked constriction of the pupils (pinpoint pupils); exhibits muscle twitching; has involuntary urination and bowel movement. Severe poisonings are indicated by incontinence, unconsciousness and seizures.

 

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)

Pirimicarb

23103-98-2

500g/kg

not set

not set

Calcium carbonate

471-34-1

320g/kg

10

not set

Other non hazardous ingredients

secret

to 100%

not set

not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.

If swallowed, splashed on skin or inhaled, contact a Poisons Information Centre or a doctor at once. Remove any contaminated clothing and wash skin thoroughly. If swallowed, use of activated charcoal may be advised.

Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.

Skin Contact: Quickly and gently brush away excess solids. Wash gently and thoroughly with warm water (use non- abrasive soap if necessary) for 10-20 minutes or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or discard.

Eye Contact: Quickly and gently brush particles from eyes. No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.

Ingestion: If swallowed, do NOT induce vomiting; rinse mouth thoroughly with water and contact a Poisons Information Centre, or call a doctor at once. Give activated charcoal if instructed.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. This product, if scattered, may form flammable or explosive dust clouds in air.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is liquid-tight chemical protective clothing and breathing apparatus.

Flash point:

Combustible solid.

Upper Flammability Limit:

No data.

Lower Flammability Limit:

No data.

Autoignition temperature: 

No data.

Flammability Class: 

No data.

section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that dusts are likely to build up in cleanup area, we recommend that you use a suitable Dust Mask. Use a P1 mask, designed for use against mechanically generated particles eg silica & asbestos. Otherwise, not normally necessary.

Stop leak if safe to do so, and contain spill. Because of the toxicity of this product, special personal care should be taken in any cleanup operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Consider vacuuming if appropriate. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.

Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Store in a cool, well ventilated area. Check containers periodically for leaks. Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. If you keep more than 10000kg or L of Dangerous Goods of Packaging Group III, you may be required to license the premises or notify your Dangerous Goods authority. If you have any doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)

Calcium carbonate

10

not set

The ADI for Pirimicarb is set at 0.002mg/kg/day. The corresponding NOEL is set at 0.4mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, June 2014.

No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below the TWA levels. If necessary, use a fan.

Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.

Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.

Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC.

Respirator:

If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable Dust Mask. Use a P1 mask, designed for use against mechanically generated particles eg silica & asbestos. Otherwise, not normally necessary.

Safety deluge showers should, if practical, be provided near to where this product is being used.

section 9 - Physical and Chemical Properties: 
Physical Description & colour:

Off-white granulated solid.

Odour:

No data.

Boiling Point:

Not available.

Freezing/Melting Point:

Pirimicarb melts approx 92°C

Volatiles:

No specific data. Expected to be low at 100°C.

Vapour Pressure:

Pirimicarb 0.97mPa at 25°C

Vapour Density:

No data.

Specific Gravity:

No data. Bulk density 0.61

Water Solubility:

Soluble.

pH:

No data.

Volatility:

No data.

Odour Threshold:

No data.

Evaporation Rate:

No data.

Coeff Oil/water distribution:

1.7 (unionised) (log P octanol/water)

Autoignition temp:

No data.

section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Containers should be kept dry. Keep isolated from combustible materials. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.

Incompatibilities: strong acids, strong bases, strong oxidising agents.

Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Oxides of sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water, sodium compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.

Polymerisation: This product will not undergo polymerisation reactions.

section 11 - Toxicological Information: 

Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.

The following data is for Pirimicarb

ACUTE TOXICITY DERMAL: LD50 = >500mg/kg (rat); nonirritant.

ORAL: LD50 = 147mg/kg (rat) LD50 = 107mg/kg (mouse); 25-50mg/kg (poultry); 100-200mg/kg (dog).

INHALATION: LC50 (rat) 0.3mg/L (6 hours) - Pesticides Manual

EYES: Pirimicarb caused no irritation when introduced as a 5% solution of technical material into the eyes of rabbits.

SUBACUTE AND CHRONIC TOXICITY:

Rat: No ill effects were detected when rats were fed 750 ppm for 90 days. Dog: In feeding tests for a period of 90 days, a no-effect level of 1.8 mg/kg was demonstrated. Daily application of 500mg/kg to rabbits (dermally) for 24 hours over a 14 day period produced no toxic signs during the experiment or during the next 14 days. Rats exposed for 6 hr/d (5 d/week) for 21 d, to air which had been passed over technical Pirimicarb at room temperature developed no toxic sign, nor was there inhibition of cholinesterase.

Daily applications of 500 mg/kg (for 24-hr) to rabbit skin over a 14-day period produced no toxic symptom. In 2-yr feeding trials NEL was: for dogs 1.8mg/kg daily; for rats 250 mg/kg diet (12.5mg/kg daily).

Classification of Hazardous Ingredients

Ingredient

Risk Phrases

Pirimicarb

Conc>=25%: T; R25

Acute toxicity - category 3

  • Hazardous to the aquatic environment (acute) - category 1
  • Hazardous to the aquatic environment (chronic) - category 1 

Potential Health Effects

See above for Chronic exposure studies.
Inhalation:
Short term exposure: Long term inhalation of high amounts of any nuisance dust may overload lung clearance
mechanism. Symptoms are described fully above.
Skin Contact:
Short term exposure: Symptoms are described fully above.
Eye Contact:
Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild
transient discomfort.
Ingestion:
Short term exposure: Symptoms are described fully above.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.

section 12 - Ecological Information: 

This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.

Pirimicarb presents some hazard to fish, birds, and beneficial insects. Some hazard to honey bees. Biological magnification unlikely. Nonphytotoxic. Does not harm lady birds or lacewings. Low bee toxicity. LC50 (96-hr) is: for bluegill 55mg/l; for rainbow trout 29 mg/l. Acute oral LD50 for mallard duck 17.2mg/kg; for bobwhite quail 8.2mg/kg.

Approximate Residual Period: Relatively short in plants; broken down rapidly by ultraviolet light.

section 13 - Disposal Considerations: 

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.

section 14 - Transport Information: 

Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.

UN Number: 2757, CARBAMATE PESTICIDE, SOLID, TOXIC

Hazchem Code: 2X

Special Provisions: 61, 223, 274

Limited quantities: ADG 7 specifies a Limited Quantity value of 5 kg for this class of product.

Dangerous Goods Class: Class 6.1, Toxic Substances.

Packing Group: III

Packing Instruction: P002, IBC08, LP02

Class 6 Toxic Substances shall not be loaded in the same vehicle or packed in the same freight container with Classes 1 (Explosives), 3 (Flammable Liquids where the Flammable Liquid is nitromethane), 5.1 (Oxidising Agents where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides where the Toxic Substances are Fire Risk Substances), 8 (Corrosive Substances where the Toxic Substances are cyanides and the Corrosives are acids), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the same freight container with Classes, 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Toxic Gases), 3 (Flammable liquids, except where the flammable liquid is nitromethane), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents except where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides except where the Toxic Substances are Fire Risk Substances), 7 (Radioactive Substances), 8 (Corrosive Substances except where the Toxic Substances are cyanides and the Corrosives are acids), 9 (Miscellaneous Dangerous Goods)

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations. The following ingredient; Pirimicarb is listed in the SUSMP.

section 16 - Other Information: 

This SDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW
TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW
THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.

Please read all labels carefully before using product.

This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice” (December 2011)
Copyright © Kilford & Kilford Pty Ltd, July, 2016.
http://www.kilford.com.au/ Phone (02)9251 4532