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Farmozine® WG

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Atrazine is a 1,3,5-triazine derivative.

Trade Name: 

Farmozine 900 WG Herbicide

Product Use: 

Agricultural herbicide for use as described on the product label.

Creation Date: 

July, 2002

This version issued: 

August, 2012 and is valid for 5 years from this date.

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: Hazardous according to the criteria of SWA Australia.

Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this MSDS.

Risk Phrases: R36, R43, R40, R20/22. Irritating to eyes. May cause sensitisation by skin contact. Harmful: possible risk of irreversible effects. Harmful through inhalation, and if swallowed.

Safety Phrases: S2, S20, S25, S28, S38, S46, S36/37. Keep out of reach of children. When using, do not eat or drink. Avoid contact with eyes. After contact with skin, wash immediately with plenty of water. In case of insufficient ventilation, wear suitable respiratory equipment. If swallowed, contact a doctor or Poisons Information Centre immediately and show this container or label. Wear suitable protective clothing and gloves.

SUSMP Classification: S5

ADG Classification: Class 9: Miscellaneous dangerous goods.

UN Number: 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Emergency Overview

Physical Description & colour: Light tan coloured granules.

Odour: Mild, sweet odour.

Major Health Hazards: Atrazine is slightly to moderately toxic to humans and other animals. It can be absorbed orally, dermally, and by inhalation. Symptoms of poisoning include abdominal pain, diarrhoea and vomiting, eye irritation, irritation of mucous membranes, and skin reactions.

Potential Health Effects

See section 11 for Chronic exposure studies.

Inhalation:

Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In addition, this product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Skin Contact:

Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a sensitiser, once sensitisation has occurred, may manifest itself as an asthmatic condition, and in some individuals this reaction can be extremely severe. In addition, this product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Eye Contact:

Short term exposure: Available data shows that this product is not harmful. In addition, this product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage.

Ingestion:

Short term exposure: This product is harmful if swallowed. See symptoms above.

Carcinogen Status:

SWA: No significant ingredient is classified as carcinogenic by SWA.

NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: Atrazine is Class 3 - unclassifiable as to carcinogenicity to humans.

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)

Atrazine

1912-24-9

90 5

not set

Other non hazardous ingredients

secret to 100

not set

not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia and is available at all times. Have this MSDS with you when you call.

Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.

Skin Contact: If poisoning occurs, contact a Poisons Information Centre, or call a doctor at once. Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed.

Eye Contact: Quickly and gently blot or brush away product. Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the unaffected eye or onto the face.

Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire.

Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is full fire kit and and breathing apparatus.

Flash point:

No data

Upper Flammability Limit:

No data

Lower Flammability Limit:

No data

Autoignition temperature: 

No data

Flammability Class: 

No data

section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective clothing including face mask, face shield and gauntlets. All skin areas should be covered. See above under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, PVC. Stop leak if safe to do so, and contain spill. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.

Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this class of poison. Make sure that containers of this product are kept tightly closed. Make sure that the product does not come into contact with substances listed under "Materials to avoid" in Section 10. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)

Atrazine

5

not set

The ADI for Atrazine is set at 0.005mg/kg/day. The corresponding NOEL is set at 0.5mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Sept 2011.

Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that dusts are minimised.

Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where this product is being used.

Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.

Protective Material Types: We suggest that protective clothing be made from the following: rubber, PVC.

Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable Dust Mask. Use a P3 mask, designed for use against all particulates including highly toxic materials. Otherwise, not normally necessary.

Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being used.

section 9 - Physical and Chemical Properties: 
Physical Description & colour:

Light tan coloured granules.

Odour:

Mild, sweet odour.

Boiling Point:

No specific data. Expected to decompose before boiling.

Freezing/Melting Point:

No specific data. Atrazine melts about 176°C

Volatiles:

No specific data. Expected to be low at 100°C.

Vapour Pressure:

No data. Expected to be negligible at normal room temperatures.

Vapour Density:

No data.

Specific Gravity:

No data.

Water Solubility:

Dispersible.

pH:

No data.

Volatility:

No data.

Odour Threshold:

No data.

Evaporation Rate:

No data.

Coeff Oil/water distribution:

No data.

Autoignition temp:

No data.

section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C.

Incompatibilities: strong oxidising agents.

Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Hydrogen cyanide poisoning signs and symptoms are weakness, dizziness, headache, nausea, vomiting, coma, convulsions, and death. Death results from respiratory arrest. Hydrogen cyanide gas acts very rapidly; symptoms and death can both occur quickly.

Polymerisation: This product is unlikely to undergo polymerisation processes.

section 11 - Toxicological Information: 

Toxicity: 

Acute toxicity: Atrazine is slightly to moderately toxic to humans and other animals. It can be absorbed orally, dermally, and by inhalation. Symptoms of poisoning include abdominal pain, diarrhoea and vomiting, eye irritation, irritation of mucous membranes, and skin reactions. At very high doses, rats show excitation followed by depression, slowed breathing, incoordination, muscle spasms, and hypothermia. After consuming a large oral dose, rats exhibit muscular weakness, hypoactivity, breathing difficulty, prostration, convulsions, and death. Atrazine is a mild skin irritant. Rashes associated with exposure have been reported. The oral LD50 for atrazine is 3090 mg/kg in rats, 1750 mg/kg in mice, 750 mg/kg in rabbits, and 1000 mg/kg in hamsters. The dermal LD50 in rabbits is 7500 mg/kg and greater than 3000 mg/kg in rats. The 1-hour inhalation LC50 is greater than 0.7 mg/L in rats. The 4-hour inhalation LC50 is 5.2 mg/L in rats.

Chronic toxicity: Some 40% of rats receiving oral doses of 20 mg/kg/day for 6 months died with signs of respiratory distress and paralysis of the limbs. Structural and chemical changes in the brain, heart, liver, lungs, kidney, ovaries, and endocrine organs were observed. Rats fed 5 or 25 mg/kg/day of atrazine for 6 months exhibited growth retardation. In a 2-year study with dogs, 7.5 mg/kg/day caused decreased food intake and increased heart and liver weights. At 75 mg/kg/day, there were decreases in food intake and body weight gain, increased adrenal weight, lowered blood cell counts, and occasional tremors or stiffness in the rear limbs.

Reproductive effects: Dietary doses of atrazine given to rats on days 3, 6 and 9 of gestation up to about 50 mg/kg/day caused no adverse reproductive effects.

Teratogenic effects: Atrazine does not appear to be teratogenic. In mice, atrazine did not cause abnormalities in foetuses whose dams were given doses of 46.4 mg/kg/day during days 6 through 14 of gestation.

Mutagenic effects: The weight of evidence from more than 50 studies indicates that atrazine is not mutagenic.

Carcinogenic effects: Atrazine did not cause tumours when mice were given oral doses of 21.5 mg/kg/day from age 1 to 4 weeks, followed by dietary doses of 82 mg/kg for an additional 17 months. However, mammary tumours were observed in rats after lifetime administration of high doses of atrazine. This represents a common tumour at a single site and in a single sex of one species. Thus, available data regarding its carcinogenic potential are inconclusive.

Organ toxicity: Lethal doses of atrazine in test animals have caused congestion and/or haemorrhaging to the lungs, kidneys, liver, spleen, brain, and heart. Long-term consumption of high levels of atrazine has caused tremors, changes in organ weights, and damage to the liver and heart.

Fate in humans and animals: Atrazine is readily absorbed through the gastrointestinal tract. When a single dose of 0.53 mg atrazine was administered to rats by gavage, 20% of the dose was excreted in the faeces within 72 hours. The other 80% was absorbed across the lining of the gastrointestinal tract into the bloodstream. After 72 hours, 65% was eliminated in the urine and 15% was retained in body tissues, mainly in the liver, kidneys, and lungs.

section 12 - Ecological Information: 

Effects on birds: Atrazine is practically nontoxic to birds. The LD50 is greater than 2000 mg/kg in mallard ducks. At dietary doses of 5000 ppm, no effect was observed in bobwhite quail and ring-necked pheasants.

Effects on aquatic organisms: Atrazine is slightly toxic to fish and other aquatic life. Atrazine has a low level of bioaccumulation in fish. In whitefish, atrazine accumulates in the brain, gall bladder, liver, and gut.

Effects on other organisms: Atrazine is not toxic to bees.

Environmental Fate:

Breakdown in soil and groundwater: Atrazine is highly persistent in soil. Chemical hydrolysis, followed by degradation by soil microorganisms, accounts for most of the breakdown of atrazine. Hydrolysis is rapid in acidic or basic environments, but is slower at neutral pHs. Addition of organic material increases the rate of hydrolysis. Atrazine can persist for longer than 1 year under dry or cold conditions. Atrazine is moderately to highly mobile in soils with low clay or organic matter content. Because it does not adsorb strongly to soil particles and has a lengthy half-life (60 to >100 days), it has a high potential for groundwater contamination despite its moderate solubility in water. Atrazine is the second most common pesticide found in private wells and in community wells. Trace amounts have been found in drinking water samples and in groundwater samples in a number of states. A 5-year survey of drinking water wells detected atrazine in an estimated 1.7% of community water systems and 0.7% of rural domestic wells nationwide. Levels detected in rural domestic wells sometimes exceeded the MCL. The recently completed National Survey of Pesticides in Drinking Water found atrazine in nearly 1% of all of the wells tested.

Breakdown in water: Atrazine is moderately soluble in water. Chemical hydrolysis, followed by biodegradation, may be the most important route of disappearance from aquatic environments. Hydrolysis is rapid under acidic or basic conditions, but is slower at neutral pHs. Atrazine is not expected to strongly adsorb to sediments. Bioconcentration and volatilization of atrazine are not environmentally important. Atrazine has been detected in each of 146 water samples collected at 8 locations from the Mississippi, Ohio and Missouri Rivers and their tributaries. For several weeks, 27% of these samples contained atrazine concentrations above the EPA's maximum contaminant level (MCL).

Breakdown in vegetation: Atrazine is absorbed by plants mainly through the roots, but also through the foliage. Once absorbed, it is translocated upward and accumulates in the growing tips and the new leaves of the plant. In susceptible plant species, atrazine inhibits photosynthesis. In tolerant plants, it is metabolized. Most crops can be planted 1 year after application of atrazine. Atrazine increases the uptake of arsenic by treated plants.

section 13 - Disposal Considerations: 

Disposal: Instructions concerning the disposal of this product and its containers are given on the registered label. These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.

section 14 - Transport Information: 

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L) or less; or IBCs, but classed as Dangerous by IATA and IMDG when carried by Air or Sea transport (see details below).

ADG Code: 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

Hazchem Code: 2Z

Special Provisions: 179, 274, AU01

Limited quantities: ADG 7 specifies a Limited Quantity value of 5 kg for this class of product.

Dangerous Goods Class: Class 9: Miscellaneous Dangerous Goods.

Packaging Group: III

Packaging Method: P002, IBC08, LP02

Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight container with Dangerous Goods of Class 1 (Explosives).

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this product are compliant with NICNAS regulations. The following ingredient: atrazine is mentioned in the SUSMP.

section 16 - Other Information: 

Much of the Information in this MSDS came from Extoxnet, a Pesticide Information Project of Cooperative Extension Offices of Cornell University, Oregon State University, the University of Idaho, and the University of California at Davis and the Institute for Environmental Toxicology, Michigan State University.

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532