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Flagship 400

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Fluroxypyr is an aryloxyalkanoic acid derivative, present here as the meptyl ester.
Trade Name:  Flagship 400 EC Herbicide
Product Use:  Agricultural herbicide for use as described on the product label.
Creation Date:  May, 2015
This version issued:  June, 2016 and is valid for 5 years from this date.

Poisons Information Centre: Phone 13 1126 from anywhere in Australia

section 2 - Hazards Identification: 

Statement of Hazardous Nature
This product is classified as: Xi, Irritating. T, Toxic. Hazardous according to the criteria of SWA.
Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs
(refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed
as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in
Section 14 of this SDS.
SUSMP Classification: S5
ADG Classification: Class 9: Miscellaneous dangerous goods.
UN Number: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

GHS Signal word: DANGER
Flammable liquids Category 4
Skin Corrosion /Irritation Category 2
Serious eye damage/eye irritation Category 2B
Specific Target Organ Toxicity - Single Exposure Category 3
Reproductive Toxicity Category 1
HAZARD STATEMENT:
H227: Combustible liquid.
H315: Causes skin irritation.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
H360: May damage fertility or the unborn child.
PREVENTION
P102: Keep out of reach of children.
P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking.
P261: Avoid breathing fumes, mists, vapours or spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P271: Use only outdoors or in a well ventilated area.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P312: Call a POISON CENTRE or doctor if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313: If exposed or concerned: Get medical advice.
P332+P313: If skin irritation occurs: Get medical advice.
P337+P313: If eye irritation persists: Get medical advice.
P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the
preferred firefighting medium but, if it is not available, normal foam can be used.
STORAGE
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL
P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour: Amber to brown coloured liquid.
Odour: Hydrocarbon odour.
Major Health Hazards: Acute toxicity. Fluroxypyr MHE has low acute toxicity. The rat oral LD50 is >5000 mg/kg,
the rabbit dermal LD50 is >2000 mg/kg, and the rat inhalation LC50 is >1.0 mg/l, the maximum attainable
concentration. Fluroxypyr MHE is not a skin sensitizer in guinea pigs, has no dermal irritation in rabbits, and shows
mild ocular irritation in rabbits.
This product may cause harm to unborn children, irritating to eyes, respiratory system and skin.

See section 11 for Chronic exposure studies.

 

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Fluroxypyr as the methylheptyl ester 81406-37-3 400g/L not set not set
Aromatic hydrocarbons 64742-94-5 316g/L not set not set
N-Methyl-2-pyrrolidone 872-50-4 100g/L 103 309
Other non hazardous ingredients secret to 100 not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: If irritation occurs, contact a Poisons Information Centre, or call a doctor. Remove source of
contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained
personnel, preferably on a doctor's advice. In severe cases, symptoms of pulmonary oedema can be delayed up to 48
hours after exposure.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is little risk of an explosion from this product if commercial quantities are involved
in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquid.

Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces,
forming potentially explosive mixtures. They may also flash back considerable distances.
Fire decomposition products from this product are likely to be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Try to contain spills, minimise spillage entering drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of
a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal
protective equipment is full fire kit and breathing apparatus.
Flash point: >62°C
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: Flammable Category 4 (GHS), C1 combustible (AS 1940)

   
   
   
   
   
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to
restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers
for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer
to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant
quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers,
spillage and unused material may be found on the label. If there is any conflict between this SDS and the label,
instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly
launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending
contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
N-Methyl-2-pyrrolidone 103 309

for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Amber to brown coloured liquid.
Odour: Hydrocarbon odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No data.
Vapour Pressure: No data.
Vapour Density: No data.
Specific Gravity: 1.0 approx.
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data.
Autoignition temp: No data.
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, wellventilated
area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke.
Water is also formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen.
Occasionally hydrogen cyanide gas in reducing atmospheres. May form hydrogen chloride gas, other compounds of
chlorine. May form hydrogen fluoride gas and other compounds of fluorine. Carbon monoxide poisoning produces
headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.

section 11 - Toxicological Information: 

Toxicity: Genotoxicity studies show a lack of genotoxicity.
Reproductive and developmental toxicity. Studies show that fluroxypyr and fluroxypyr Meptyl ester (MHE) are not
teratogenic nor will they interfere with in utero development.
Subchronic toxicity. Fluroxypyr MHE showed a NOEL of 1,000 mg/ kg/day in a 90-day rat dietary study and a 21-
day rabbit dermal study. Ninety day feeding studies with fluroxypyr showed NOELs of 80 mg/kg/day (Wistar rats), 700
mg/kg/day (Fischer 344 rats), 1342 mg/kg/day (male mice), and 1,748 mg/kg/day (female mice). In a 4-week dietary,
range finding study with fluroxypyr in dogs the NOEL was >50 mg/kg/day.
Chronic toxicity. NOELs found in chronic dietary studies are as follows: 150 mg/kg/day (dog), 300 mg/kg/day
(mouse), 80 mg/kg/day (Wistar rats), 100 mg/kg/day (male Fischer 344 rats), and 500 mg/kg/day (female Fischer 344
rats).
Animal metabolism. Studies show that fluroxypyr MHE is rapidly hydrolysed and the fate of the hydrolysis products,
fluroxypyr and 1-methylheptanol, are independent of whether they were given as the ester or the acid. Fluroxypyr, per
se, was extensively absorbed and rapidly excreted principally unchanged in the urine. 1-Methylheptanol also was
rapidly absorbed and rapidly eliminated. Repeated administration of fluroxypyr MHE was not associated with
accumulation in tissues. Also, the metabolism and pharmacokinetics of methylheptanol are comparable to that of the
methylheptyl portion of fluroxypyr MHE.
Carcinogenicity. There was no evidence of carcinogenicity in an 18-month mouse feeding study and a 24-month rat
feeding study at all dosages tested. The NOELs shown in the mouse and rat oncogenicity studies were 1,000 and 320
mg/ kg/day, respectively.

Classification of Hazardous Ingredients

Ingredient                                           Risk Phrases
N-methyl-2-pyrrolidone                Conc>=10%: T; R61; R36/37/38

There is no data to hand indicating any particular target organs.
N-methyl-2-pyrrolidone is a SWA Class 2 Reproductive risk: may cause harm to the unborn child

Potential Health Effects

Inhalation:
Short term exposure: This product is an inhalation irritant. Symptoms may include headache, irritation of nose and
throat and increased secretion of mucous in the nose and throat. Other symptoms may also become evident, but they
should disappear after exposure has ceased if treatment is prompt.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: This product is a skin irritant. Symptoms may include itchiness and reddening of contacted
skin. Other symptoms may also become evident, but if treated promptly, all should disappear once exposure has
ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is an oral
irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms may
also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.

 

section 12 - Ecological Information: 

This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
Harmful to aquatic organisms. Not toxic: birds and bees.
Mobility Soil: Moderately mobile (Fluroxypyr)
Persistence/degradability Soil:
The product is not persistent. Half-life time (t½): 5-9 days (Fluroxypyr), < 7 days (Fluroxypyr-meptyl)
Degradation is primarily via: microorganisms (Fluroxypyr) and hydrolysis (Fluroxypyr-meptyl)
Water: DT50 = 1-3 days (Fluroxypyr-methyl)
Ecotoxicity : Fish Fluroxypyr
LC50 (96 hours) rainbow trout > 100 mg/L, golden orfe > 100 mg/L , rainbow trout > 0.9 mg/L, solubility limit
(Fluroxypyr-meptyl)
golden orfe > 0.9 mg/L, solubility limit
Daphnia magna: EC50 (48 hours) > 100 mg/L (Fluroxypyr)
> 0.9 mg/L, solubility limit (Fluroxypyr-meptyl)
Green algae: EC50 (96 hours) > 100 mg/L (Fluroxypyr)
> 0.9 mg/L, solubility limit (Fluroxypyr-meptyl)
Birds: Bobwhite quail LD50 > 2,000 mg/kg (Fluroxypyr-meptyl & Fluroxypyr)
Mallard duck LD50 > 2,000 mg/kg (Fluroxypyr-meptyl & Fluroxypyr)
Bees: Oral LD50 > 100 μg/bee (Fluroxypyr-meptyl), Contact LD50 > 100 μg/bee (Fluroxypyr-meptyl)
Contact LD50 > 25 μg/bee (Fluroxypyr)

section 13 - Disposal Considerations: 

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general
advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of
unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the
disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for
your area.

section 14 - Transport Information: 

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L)
or less; or IBCs, but classed as Dangerous by IATA and IMDG/IMSBC when carried by Air or Sea
transport (see details below).
UN Number: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazchem Code: •3Z
Special Provisions: 179, 274, 331, 335, AU01
Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.
Dangerous Goods Class: Class 9: Miscellaneous Dangerous Goods.
Packing Group: III
Packing Instruction: P001, IBC03, LP01
Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight
container with Dangerous Goods of Class 1 (Explosives).

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Fluroxypyr, Aromatic hydrocarbons, N-Methyl-2-pyrrolidone, are mentioned in the SUSMP.

section 16 - Other Information: 

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532