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Legacy® MA

Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700


Chemical nature: 

Blend of Diflufenican and MCPA in a suitable solvent system.
Trade Name:  Legacy MA Herbicide
Product Use:  Agricultural herbicide for use as described on the product label.
Creation Date:  December, 2008
This version issued:  August, 2012 and is valid for 5 years from this date.


section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA.
Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG respectively. See details below and in Section 14 of this MSDS. However, this is a C1 Combustible Liquid so must be stored and handled as specified in AS 1940 “The storage and handling of flammable and combustible liquids.”
Risk Phrases: R65, R66, R20/21/22, R51/53. Harmful: May cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. Harmful by inhalation, in contact with skin, and if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment.
Safety Phrases: S2, S13, S20, S29, S35, S38, S46, S57, S61, S20/21, S24/25, S36/37/39. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. When using, do not eat or drink. Do not empty into drains. This material and its container must be disposed of in a safe way. In case of insufficient ventilation, wear suitable respiratory equipment. If swallowed, contact a doctor or Poisons Information Centre immediately and show this MSDS or label. Use appropriate container to avoid environmental contamination. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. When using, do not eat, drink or smoke. Avoid contact with skin and eyes. Wear suitable protective clothing, gloves and eye/face protection.
SUSMP Classification: S5
Dangerous Goods Classification: Class 9: Miscellaneous dangerous goods.

Emergency Overview

Physical Description & colour: Dark brown liquid.
Odour: Characteristic solvent odour.
Major Health Hazards: harmful by inhalation, in contact with skin, and if swallowed, if aspirated, may cause lung damage, repeated exposure may cause skin dryness or cracking.

Potential Health Effects

Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.

Eye Contact:
Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term eye exposure.
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to remove and can cause severe injury or death. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.




section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Diflufenican 83164-33-4 25g/L not set not set
MCPA (as 2-hexyl ethyl ester) 29450-45-1 250g/L not set not set
N-Methyl-2-pyrrolidone 872-50-4 14-16% 103 309
Aromatic hydrocarbons 64742-94-5 31-34% not set not set
Other non hazardous ingredients secret to 100% not set not set


This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call.
Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts) and completely decontaminate them before reuse or discard.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is little risk of an explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back considerable distances.
Fire decomposition products from this product are likely to be toxic and corrosive if inhaled. Take appropriate protective measures.

Extinguishing Media: Try to contain spills, minimise spillage entering drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is full fire kit and and breathing apparatus.

Flash point: >65°C
Upper Flammability Limit: 7%
Lower Flammability Limit: 1%
Autoignition temperature:  No data.
Flammability Class:  C1
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full protective clothing including eye/face protection. All skin areas should be covered. See below under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include no specific manufacturer recommendations. Use impermeable gloves with care. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. It should be fitted with a type G cartridge, suitable for agricultural chemicals. Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Because of the environmentally hazardous nature of this product, special care should be taken to restrict release to waterways or drains. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this schedule of poison. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
N-Methyl-2-pyrrolidone 103 309

The ADI for Diflufenican is set at 0.2mg/kg/day. The corresponding NOEL is set at 16.3mg/kg/day.
The ADI for MCPA is set at 0.01mg/kg/day. The corresponding NOEL is set at 1.1mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Sept 2011.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.

Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.
Protective Material Types: There is no data that enables us to recommend any type except that it should be impermeable.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. Otherwise, not normally necessary.
Safety deluge showers should, if practical, be provided near to where this product is being used.

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Dark brown liquid.
Odour: Characteristic solvent odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No data.
Vapour Pressure: 4.25 x 10-3 mPa @ 25°C (Diflufenican)
Vapour Density: No data.
Specific Gravity: 0.985-1.015 at 20°C
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: 4.9 (Diflufenican) (log P octanol/water)
Autoignition temp: No data.
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: acids, bases, oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Hydrogen chloride gas, other compounds of chlorine. Hydrogen fluoride gas and other compounds of fluorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.

section 11 - Toxicological Information: 

Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.
An information profile for MCPA is available at
Acute toxicity: MCPA acid is harmful via ingestion, with reported oral LD50 values for the technical product in rats ranging from 700 mg/kg to 1160 mg/kg and ranging in mice from 550 to 800 mg/kg. It is harmful via the dermal route as well, with reported dermal LD50 values ranging from greater than 1000 mg/kg in rats to greater than 4000 mg/kg in rabbits.
Chronic toxicity: Dietary levels of approximately 50 mg/kg/day and 125 mg/kg/day over 7 months caused reduced feeding rates and retarded growth rates in rats. White blood cell counts and ratios were not affected, but some reductions in red blood cell counts and haemoglobin did appear to be associated with exposure to MCPA at oral dose levels of approximately 20 mg/kg/day. In the same study, oral doses of approximately 5 mg/kg/day caused increased relative kidney weights, and oral doses of approximately 20 mg/kg/day caused increased relative liver weights. Another study in rats showed no effects on kidney or liver weights over an unspecified period at oral doses of 60 mg/kg/day, but oral doses of 150 mg/kg/day did cause reversible increases in these weights over a course of 3 months. Very high dermal doses of 500 mg/kg/day caused reduced body weight, and even higher dermal doses of 1000 and 2000 mg/kg/day resulted in increased mortality and observable changes in liver, kidney, spleen, and thymus tissue.

Reproductive effects: A two-generation rat study at doses of up to 15 mg/kg/day affected reproductive function. It is unlikely that humans will experience these effects under normal exposure conditions.
Teratogenic effects: Offspring of pregnant rats fed low to moderate doses of MCPA (20 to 125 mg/kg) on days 6 to 15 of gestation, had no birth defects. Teratogenic effects in humans are unlikely at expected exposure levels.
Mutagenic effects: MCPA is reportedly weakly mutagenic to bone marrow and ovarian cells of hamsters, but negative results were reported for other mutagenic tests. It appears that the compound poses little or no mutagenic risk.
Carcinogenic effects: All of the available evidence on MCPA indicates that the compound does not cause cancer. Forestry and agricultural workers occupationally exposed to MCPA in Sweden did not show increased cancer incidence.
Organ toxicity: Target organs identified in animal studies include the liver, kidneys, spleen. and thymus. Farm worker exposure has resulted in reversible anaemia, muscular weakness, digestive problems, and slight liver damage.
Fate in humans and animals: MCPA is rapidly absorbed and eliminated from mammalian systems. Rats eliminated nearly all of a single oral dose within 24 hours, mostly though urine with little or no metabolism. Humans excreted about half of a 5 mg dose in the urine within a few days. No residues were found after day 5.
NOAEL: rat = 500 ppm or 25 mg/kg/day (2 years): mice = 500 ppm or 60-73 mg/kg/day (2 years)
NOEL : dog = 100 mg/kg/day
Chronic toxicity
Mutagenicity: Not mutagenic
Reproduction toxicity NOEL (rat) = 200 ppm ( 3 generation)
Teratogenicity: NOEL (rat) > 1,000 mg/kg/day
NOEL (rabbit) > 1,000 mg/kg/day Classification of Hazardous Ingredients
Ingredient Risk Phrases
N-methyl-2-pyrrolidone Conc>=10%: Xi; R36/38 MCPA Conc>=25%: Xn; R22; R38; R41 Aromatic Hydrocarbons Conc>=10%: Xn; R65

Classification of Hazardous Ingredients

Ingredient                                                                                      Risk Phrases
N-methyl-2-pyrrolidone                                                                Conc>=10%: Xi; R36/38

MCPA                                                                                             Conc>=25%: Xn; R22; R38; R41

Aromatic Hydrocarbons                                                                  Conc>=10%: Xn; R65

section 12 - Ecological Information: 

Toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment. This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
Effects on birds: MCPA is moderately toxic to wildfowl; the LD50 of MCPA in bobwhite quail is 377 mg/kg.
Effects on aquatic organisms: MCPA is only slightly toxic to freshwater fish, with reported LC50 values ranging from 117 to 232 mg/L in rainbow trout. MCPA is practically nontoxic to freshwater invertebrates, and estuarine and marine organisms.
Effects on other organisms: It is nontoxic to bees, with a reported oral LD50 of 104μg/bee.
Environmental Fate:
Breakdown in soil and groundwater: MCPA and its formulations are rapidly degraded by soil microorganisms and it has low persistence, with a reported field half-life of 14 days to 1 month, depending on soil moisture and soil organic matter. MCPA and its formulations show little affinity for soil.
Breakdown in water: It is relatively stable to light breakdown , but can be rapidly broken down by microorganisms. In rice paddy water, MCPA is almost totally degraded by aquatic microorganisms in under 2 weeks.
Mobility Low mobility.
Persistence/degradability Half-life time (t½): 105-210 days.
Ecotoxicity :
Birds: Bobwhite quail LD50 > 2,150 mg/kg Mallard duck LD50 > 4,000 mg/kg
Fish: LC50 (96 hours) rainbow trout = 56-100 mg/L carp = 105 mg/L
algae > 10 mg/L
LC50 (48 hours) daphnia > 10 mg/L
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Birds: Low toxicity. Bees: Not toxic.

section 13 - Disposal Considerations: 

Disposal: Instructions concerning the disposal of this product and its containers are given on the registered label. These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 and for help with the disposal of empty drums, contact DrumMuster where you will find contact details for your area.

section 14 - Transport Information: 

Not subject to the ADG Code when transported by Road or Rail in Australia, in packages 500kg(L) or less; or IBCs, but classed as Dangerous by IATA and IMDG when carried by Air or Sea transport (see details below).
Hazchem Code: •3Z
Special Provisions: 179, 274, AU01
Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.
Dangerous Goods Class: Class 9: Miscellaneous Dangerous Goods.
Packaging Group: III
Packaging Method: P001, IBC03, LP01
Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight container with Dangerous Goods of Class 1 (Explosives).

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: MCPA, Aromatic hydrocarbons, are mentioned in the SUSMP.

section 16 - Other Information: 

This MSDS contains only safety-related information. For other data see product literature.

ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number


Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700


Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)


If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. Phone (02)9251 4532