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Lonestar 750 WG

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Triasulfuron is a sulfonylurea derivative
Trade Name:  Lonestar 750 WG Herbicide
Product Use:  Agricultural herbicide for use as described on the product label
Creation Date:  March, 2003
This version issued:  September, 2016 and is valid for 5 years from this date. 

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: N, Dangerous to the environment. Not classified as hazardous according to the criteria of SWA Australia.

Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.

SUSMP Classification: None allocated.

ADG Classification: None allocated. Not a Dangerous Good.

UN Number: None allocated 

GHS Signal word: NONE. Not hazardous.
Hazardous to aquatic environment Short term/Acute Category 2
HAZARD STATEMENT:
H401: Toxic to aquatic life.
PREVENTION
P102: Keep out of reach of children.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
RESPONSE
P337: If eye irritation persists: seek medical attention.
P352: Wash with plenty of soap and water.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P370+P378: Not combustible. Use extinguishing media suited to burning materials.
STORAGE
P410: Protect from sunlight.
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL
P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour: Grey to beige granules.
Odour: Mild, non-specific odour.
Major Health Hazards: No significant risk factors have been found for this product. 

 

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Triasulfuron

82097-50-5 

75 

not set 

not set 

Other non hazardous ingredients secret to 100 not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this SDS with you when you call.

Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed. If in doubt obtain medical advice.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.
Ingestion: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. 

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. This product, if scattered, may form flammable or explosive dust clouds in air.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.

Fire Fighting: When fighting fires involving significant quantities of this product, wear a splash suit complete with self contained breathing apparatus. Do not scatter spilled material with high pressure water jets. 

Flash point: Not flammable
Upper Flammability Limit: No data
Lower Flammability Limit: No data
Autoignition temperature:  No data
Flammability Class:  No data 
section 6 - Accidental Release Measures: 

Accidental release: Minor spills do not normally need any special cleanup measures. In the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Stop leak if safe to do so, and contain spill. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry. 

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.

Storage: Make sure that containers of this product are kept tightly closed. Keep containers of this product in a well ventilated area. Make sure that the product does not come into contact with substances listed under "Materials to avoid" in Section 10. Check packaging - there may be further storage instructions on the label. 

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
- - -

Exposure limits have not been established by SWA for any of the significant ingredients in this product. 

Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that dusts are minimised.
Eye Protection:

Eye protection is not normally necessary when this product is being used. However, if in doubt, wear suitable protective glasses or goggles.

Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when handling this product.

Protective Material Types: There is no specific recommendation for any particular protective material type.

Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable Dust Mask. 

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Grey to beige granules.
Odour: Mild, non-specific odour.
Boiling Point: No specific data. Expected to decompose before boiling.
Freezing/Melting Point: No specific data. Solid at normal temperatures. Technical grade active ingredient melts at about 175-180°C
Volatiles: No specific data. Expected to be low at 100°C.
Vapour Pressure: 2x10-3mPa at 25°C (Triasulfuron)
Vapour Density: No data.
Specific Gravity: No data. Bulk density about 0.5
Water Solubility: Wettable. Ingredients disperse well.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: 1.1 at pH 5.0 (log P octanol/water) (Triasulfuron)
Autoignition temp: No data.
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
 

Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Containers should be kept dry. Protect this product from light.

Incompatibilities: strong oxidising agents.
 

Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Hydrogen cyanide poisoning signs and symptoms are weakness, dizziness, headache, nausea, vomiting, coma, convulsions, and death. Death results from respiratory arrest. Hydrogen cyanide gas acts very rapidly; symptoms and death can both occur quickly.

Polymerisation: This product is unlikely to undergo polymerisation processes. 

section 11 - Toxicological Information: 

Toxicity: Triasulfuron: LD50 Oral, Rat >5000mg/kg LD50 Oral, Mouse = >5000mg/kg
LD50 Dermal, Rat = >2000mg/kg
LC50 Inhalation, Rat = >5.18mg/L/4hr 

Carcinogen Status:

SWA: No significant ingredient is classified as carcinogenic by SWA.

NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: No significant ingredient is classified as carcinogenic by IARC. 

section 12 - Ecological Information: 

Effects on Birds: Triasulfuron has very low avian toxicity. The oral LD50 value for quail and ducks is greater than 2150 mg/kg
Effects on Aquatic Organisms: The chemical has very low toxicity to aquatic organisms. 96-hour LC50 values are greater than 100 mg/l in rainbow trout, carp, catfish, sheepshead minnow and bluegill sunfish. 96 hour toxicity tests with the freshwater invertebrate Daphnia magna resulted in a LC50 of greater than 100 mg/l.

Effects on Other Animals: Triasulfuron has very low acute toxicity to honey bees with a topical LD50 of greater than 100 μg/bee. The LC50 for earthworms is greater than 1,000 mg/kg soil (14 day).
Algae:
Very toxic to algae.

EC50 (5-14 day) Green Selenastrum 0.035 mg/L

EC50 (5-14 day) Algae, Scenedesmus: 0.77 mg/L

EC50 (5-14 day) Algae, Anabaena: 1.7 mg/L

EC50 (5-14 day) Algae, Navicula: >100 mg/L

Aquatic Organisms:

Considered to be very toxic to aquatic organisms.

Environmental fate:
Animals: In animals, mainly excreted in the urine in unchanged form.
DT50 in forage is about 3 days. In straw and grain, no residues were detectable at harvest time.
Soil/environment: The degradation behavior in soil is determined by the soil type, pH and especially temperature and moisture content. Field studies with silty loam, clay loam and sandy loam showed a median DT50 of 19 days, varying with soil type. 

section 13 - Disposal Considerations: 

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area. 

section 14 - Transport Information: 

UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special transport conditions are necessary unless required by other regulations. 

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this product are compliant with NICNAS regulations. 

section 16 - Other Information: 

This SDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This SDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532