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  1. Definitions and Interpretation

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Safari 750

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Triclopyr is an aryloxyalkanoic acid derivative. It is present here as the butoxyethyl ester.
Trade Name:  Safari 750 EC Herbicide
Product Use:  Agricultural herbicide for use as described on the product label.
Creation Date:  August, 2016
This version issued:  August, 2016 and is valid for 5 years from this date.
Poisons Information Centre: Phone 13 1126 from anywhere in Australia

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature
This product is classified as: Xn, Harmful. Xi, Irritating. Hazardous according to the criteria of SWA.
Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA or IMDG/IMSBC criteria.
SUSMP Classification: S6
ADG Classification: None allocated. Not a Dangerous Good according to Australian Dangerous Goods (ADG)
Code, IATA or IMDG/IMSBC criteria.
UN Number: None allocated

GHS Signal word: WARNING
Flammable liquids Category 4
Acute Toxicity Oral Category 4
Skin Corrosion /Irritation Category 2
Serious eye damage/eye irritation Category 2B
Specific Target Organ Toxicity - Single Exposure Category 3
HAZARD STATEMENT:
H227: Combustible liquid.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H320: Causes eye irritation.
H335: May cause respiratory irritation.
PREVENTION
P102: Keep out of reach of children.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P362: Take off contaminated clothing and wash before reuse.
P301+P310: IF SWALLOWED: Immediately call a POISON CENTRE or doctor.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice.
P337+P313: If eye irritation persists: Get medical advice.
P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog.

STORAGE
P410: Protect from sunlight.
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
DISPOSAL
P501: Dispose of contents and containers as specified on the registered label.

Emergency Overview

Physical Description & colour: Amber coloured liquid.
Odour: Characteristic solvent odour.
Major Health Hazards: irritating to eyes and skin, harmful if swallowed, if aspirated, may cause lung damage.

See section 11 for Chronic exposure studies.

Inhalation:

Short term exposure: Placeholder

Long term exposure: Placeholder

Skin Contact:

Short term exposure: Placeholder

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Triclopyr (as butoxyethanol ester) 64700-56-7 750g/L not set not set
Liquid hydrocarbon 8008-20-6 100-300g/L not set not set
Other non hazardous ingredients secret to 100 not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 15 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: The major hazard in fires is usually inhalation of heated and toxic or oxygen
deficient (or both), fire gases. There is little risk of an explosion from this product if commercial quantities are involved
in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: In case of fire, use carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.

Flash point: >93°C
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature:  No data.
Flammability Class:  No data.
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this SDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is GHS Flammable Class 4 and therefore, for Storage, meets the definition of
Dangerous Goods. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods authority in order to clarify your obligations regarding their storage.
Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct
sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in
Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
  - -

No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should, if practical, be provided near to where this product
is being handled commercially.

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Amber coloured liquid.
Odour: Characteristic solvent odour.
Boiling Point: About 200°C at 100kPa
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No specific data. Expected to be low at 100°C.
Vapour Pressure: No data.
Vapour Density: No data.
Specific Gravity: About 1.20
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data.
Autoignition temp: No data.
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, wellventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Combustion forms carbon dioxide, and if incomplete, carbon monoxide and possibly smoke.
Water is also formed. May form nitrogen and its compounds, and under some circumstances, oxides of nitrogen.
Occasionally hydrogen cyanide gas in reducing atmospheres. Carbon monoxide poisoning produces headache,
weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed
by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.

section 11 - Toxicological Information: 

Local Effects:
Target Organs: There is no data to hand indicating any particular target organs.

Classification of Hazardous Ingredients

Ingredient                                                                             Risk Phrases
Triclopyr                                                                               Conc>=25%: Xn; R22
Liquid Hydrocarbon                                                             Conc>=10%: Xn; R65
- Aspiration hazard - category 1

Potential Health Effects

Inhalation:
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: This product is a skin irritant. Symptoms may include itchiness and reddening of contacted
skin. Other symptoms may also become evident, but if treated promptly, all should disappear once exposure has
ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this
product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to
remove and can cause severe injury or death. However, this product is an oral irritant. Symptoms may include burning
sensation and reddening of skin in mouth and throat. Other symptoms may also become evident, but all should
disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: No significant ingredient is classified as carcinogenic by IARC.

section 12 - Ecological Information: 

This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.

section 13 - Disposal Considerations: 

Disposal: Special help is available for the disposal of Agricultural Chemicals. The product label will give general
advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of
unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the
disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for
your area.

section 14 - Transport Information: 

UN Number: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special
transport conditions are necessary unless required by other regulations.

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Triclopyr, Liquid hydrocarbon, are mentioned in the SUSMP.

section 16 - Other Information: 

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532