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SDS PLATFORM DISCLAIMER

The data provided on the SDS Platform is intended as guide and for informational purposes only. We have used our best endeavours to replicate the information contained in the original SDS for your ease of reference. However, the SDS Platform must not be used as a replacement for the original SDS.
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Simanex® WG

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Simazine is a 1,3,5-triazine derivative
Trade Name:  Simanex 900 WG Herbicide
Product Use:  Agricultural herbicide for use as described on the product label.
Creation Date:  August, 2009
This version issued:  August, 2012 and is valid for 5 years from this date.

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: N, Dangerous to the environment. Hazardous according to the criteria of SWA.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.

Risk Phrases: R40, R50/53. Limited evidence of a carcinogenic effect. Very toxic to aquatic organisms, may cause long-term adverse effects to the aquatic environment.

Safety Phrases: S2, S13, S46, S60, S61, S20/21, S24/25, S36/37. Keep out of reach of children. Keep away from food, drink and animal feeding stuffs. If swallowed, contact a doctor or Poisons Information Centre immediately and show this MSDS or label. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. When using, do not eat, drink or smoke. Avoid contact with skin and eyes. Wear suitable protective clothing and gloves.

SUSMP Classification: None allocated.

ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.

UN Number: None allocated

Emergency Overview

Physical Description & colour: Whitish coloured granulated solid.

Odour: Faint odour.

Major Health Hazards: Limited evidence of a carcinogenic effect.

Potential Health Effects

Inhalation:

Short term exposure: Available data indicates that this product is not harmful. In addition product is unlikely to cause any discomfort or irritation.

Long term exposure: No data for health effects associated with long term inhalation.

Skin Contact:

Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.

Long term expsoure: No data for health effects associated with long term skin exposure.

Eye Contact:

Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild transient discomfort.

Long term expsoure: No data for health effects associated with long term eye exposure.

Ingestion:

Short term exposure: Significant oral exposure is considered to be unlikely. However, this product may be irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.

Long term expsoure: No data for health effects associated with long term ingestion.

Carcinogen Status:

SWA: Simazine is classified by SWA as a Class 3 Carcinogen, possibly carcinogenic to humans. See the SWA website for further details. A web address has not been provided as addresses frequently change.

NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: Simazine is Class 3 - unclassifiable as to carcinogenicity to humans. See the IARC website for further details. A web address has not been provided as addresses frequently change.

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Simazine 122-34-9 900g/kg not set not set
Other non hazardous ingredients secret to 100% not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call.

Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

Skin Contact: Gently brush away excess solids. Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until chemical is removed.

Eye Contact: Quickly and gently brush particles from eyes. No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more than a few minutes. Take special care if exposed person is wearing contact lenses.

Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.

Extinguishing Media: Suitable extinguishing media are carbon dioxide, dry chemical, foam, water fog.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.

Flash point: No data
Upper Flammability Limit: No data
Lower Flammability Limit: No data
Autoignition temperature:  No data
Flammability Class:  No data
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that dusts are likely to build up in cleanup area, we recommend that you use a suitable Dust Mask. Use a P1 mask, designed for use against mechanically generated particles eg silica & asbestos.
Stop leak if safe to do so, and contain spill. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Consider vacuuming if appropriate. Recycle containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.

Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.
Storage: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment:

Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
Exposure limits have not been established by SWA for any of the significant ingredients in this product. - -

The ADI for Simazine is set at 0.005mg/kg/day. The corresponding NOEL is set at 0.5mg/kg/day. ADI means Acceptable Daily Intake; NOEL means No-observable-effect-level. Taken from Australian ADI List, Dec 2008.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.

Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a fan is suggested.

Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used.

Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable impervious elbow-length gloves and facial protection when handling this product. See below for suitable material types.

Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC.

Respirator: If there is a significant chance that dusts are likely to build up in the area where this product is being used, we recommend that you use a suitable Dust Mask. Use a P1 mask, designed for use against mechanically generated particles eg silica & asbestos.
Safety deluge showers should, if practical, be provided near to where this product is being used.

section 9 - Physical and Chemical Properties: 
Physical Description & colour: Whitish coloured granulated solid.
Odour: Faint odour.
Boiling Point: No specific data. Expected to decompose before boiling.
Freezing/Melting Point: Simazine melts 220-222°C
Volatiles: No specific data. Expected to be low at 100°C.
Vapour Pressure: 0.003mPa at 25°C (negligible)
Vapour Density: No data.
Specific Gravity: No data.
Water Solubility: 6-7ppm at 25°C (Simazine)
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: 2.19 (log P octanol/water)
Autoignition temp: No data.
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: acids, bases, oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing atmospheres. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.

section 11 - Toxicological Information: 

Toxicity: An information profile for Simazine is available at http://extoxnet.orst.edu/pips/ghindex.html
Acute toxicity: The reported oral LD50 for technical Simazine in rats and mice is >2000 mg/kg; its dermal LD50 is >2000 mg/kg in rats and > 10,000 mg/kg in rabbits. The 4-hour inhalation LC50 in rats is 4.23mg/L. The formulated products, in most cases, are less toxic via all routes. Simazine is nonirritating to the skin and eyes of rabbits except at high doses. Symptoms exhibited by poisoned sheep included lower food intake, higher water intake, incoordination, tremors, and weakness, especially in the hindquarters.
Chronic toxicity: Some 90-day feeding studies showed reduced body weight at 67 to 100 mg/kg/day. This same effect and kidney toxicity were seen in rats at doses of 150 mg/kg/day. In 2-year chronic oral feeding studies in which rats were given daily dosages of 5 mg/kg/day of Simazine in the diet, no gross or microscopic signs of toxicity were seen. When rats were given repeated doses of 15 mg/kg/day, some liver cells degenerated during the first 3 days, but the condition did not progress. Instead, the liver adapted and the compound was metabolized. Other effects observed in test animals include tremors, damage to the testes, kidneys, liver, and thyroid, disturbances in sperm production, and gene mutations.
Reproductive effects: No adverse effects on reproductive capacity or development were observed in a three-generation study of rats fed 5 mg/kg/day Simazine. Reproductive effects are not likely in humans under normal circumstances.
Teratogenic effects: No dose-related teratogenic effects were observed when rabbits were given daily doses of 5, 75, or 200 mg/kg for days 7 through 19 of pregnancy. Simazine does not appear to be teratogenic.
Mutagenic effects: Simazine has shown negative results in a variety of mutagenicity tests on bacterial cultures. It is likely that Simazine is either nonmutagenic or weakly mutagenic.
Carcinogenic effects: Simazine was not tumorigenic in mice at the maximum tolerated dose of 215 mg/kg/day over an 18-month period. In other studies, doses as low as 5 mg/kg/day produced excess tumours (thyroid and mammary) in female rats. Because of inconsistencies in the data, it is not possible to determine Simazine's carcinogenic status.
Organ toxicity: Damage to the testes, kidneys, liver, and thyroid has been observed in test animals.
Fate in humans and animals: Studies in rats, goats, and sheep reveal that 60 to 70% of the ingested dose may be absorbed into the system, with approximately 5 to 10% distributed systemically to tissues. The remainder is eliminated via urine within 24 hours. It has been reported that Simazine residues were present in the urine of sheep for up to 12 days after administration of a single oral dose. The maximum concentration in the urine occurred from 2 to 6 days after administration.

Classification of Hazardous Ingredients

Ingredient                                                     Risk Phrases
Simazine                                                       Conc>=1%: Xn; R40

section 12 - Ecological Information: 

Effects on birds: Simazine is practically nontoxic to birds. The reported LD50 values in mallard and Japanese quail are >2000 mg/kg and >5000 mg/kg, respectively. The acute dietary LD50 values in hens and pigeons are both greater than 5000 ppm. The 8-day dietary LC50 in bobwhite quail is >5260 ppm and in mallard ducks is >10,000 ppm.
Effects on aquatic organisms: Simazine is slightly to practically nontoxic to aquatic species. The 96-hour LC50 for Simazine is >100 mg/L in rainbow trout, 90 mg/L in bluegill sunfish. EC50 Daphnia (48hrs) >100mg/L. A 96-hour LC50 of >3.7 mg/L is reported in oysters.
Effects on other organisms: While many mammals may be insensitive to Simazine, sheep and cattle are especially sensitive. Simazine is nontoxic to bees. A soil LC50 in earthworms of >1000 mg/kg has been reported.

Environmental Fate:
Breakdown in soil and groundwater: Simazine is moderately persistent with an average field half-life of 60 days. Soil half-lives of 28-149 days have been reported. Residual activity may remain for a year after application (2 to 4 kg/ha) in high pH soils. Simazine is moderately to poorly bound to soils. It does, however, adsorb to clays and mucks. Its low water solubility, however, makes it less mobile, limiting its leaching potential. Simazine has little, if any, lateral movement in soil, but can be washed along with soil particles in runoff. Simazine is subject to decomposition by ultraviolet radiation, but this effect is small under normal field conditions. Loss from volatilization is also insignificant. In soils, microbial activity probably accounts for decomposition of a significant amount of Simazine in high pH soils. In lower pH soils, hydrolysis will occur.
Breakdown in water: The average half-life of Simazine in ponds where it has been applied is 30 days, with the actual half-life dependent on the level of algae present, the degree of weed infestation, and other factors. Simazine may undergo hydrolysis at lower pH. It does not readily undergo hydrolysis in water at pH = 7.
Breakdown in vegetation: Plants absorb Simazine mainly through the roots, with little or no foliar penetration. From the roots, it is translocated upward to the stems, leaves, and growing shoots of the plant. It acts to inhibit photosynthesis. Resistant plants readily metabolize Simazine. Plants that are sensitive to Simazine accumulate it unchanged. It is possible that livestock or wildlife grazing on these plants could be poisoned.

section 13 - Disposal Considerations: 

Disposal: Instructions concerning the disposal of this product and its containers are given on the registered label. These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.

section 14 - Transport Information: 

ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary unless required by other regulations.

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this product are compliant with NICNAS regulations.

section 16 - Other Information: 

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532