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Wizard®

SAFETY DATA SHEET
Issued by: Adama Australia Pty Ltd Phone: (02)9431 7800 (office hours)
Poisons Information Centre: 13 1126 from anywhere in Australia,
(0800 764 766 in New Zealand)

section 1 - Identification of The Material and Supplier: 

Adama Australia Pty Ltd

Suite 1, Level 4, Building B,

207 Pacific Highway St Leonards, NSW 2065

ACN 050 328 973

Telephone (02)9431 7800 (24 hours)

Emergency 1800 024 973 (24 hours)

Fax (02)9431 7700

 

Chemical nature: 

Abamectin is a macrocyclic lactone derivative.
Trade Name:  Wizard 18 Insecticide
Product Use:  Agricultural miticide and insecticide for use as described on the product label.
Creation Date:  March, 2003
This version issued:  August, 2012 and is valid for 5 years from this date.

 

section 2 - Hazards Identification: 

Statement of Hazardous Nature

This product is classified as: Hazardous according to the criteria of SWA Australia. Dangerous according to the Australian Dangerous Goods (ADG) Code.

Risk Phrases:  R22, R23, R36/38. Harmful if swallowed. Toxic by inhalation. Irritating to eyes and skin.

Safety Phrases: S20, S38, S24/25. When using, do not eat or drink. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes.

SUSMP Classification: S6

ADG Classification: Class 6.1: Toxic substances.

UN Number: 2902, PESTICIDE, LIQUID, TOXIC, N.O.S

Emergency Overview

Physical Description & colour: Clear, colourless liquid

Odour: Characteristic odour

Major Health Hazards: Symptoms of poisoning observed in laboratory animals include pupil dilation, vomiting, convulsions and/or tremors, and coma. Abamectin acts on insects by interfering with the nervous system. At very high doses, it can affect mammals, causing symptoms of nervous system depression such as incoordination, tremors, lethargy, excitation, and pupil dilation. Very high doses have caused death from respiratory failure. Abamectin is not readily absorbed through skin.

Potential Health Effects

See section 11 for Chronic exposure studies.

Inhalation:

Short term exposure: Available data shows that this product is toxic, but symptoms are not available.

Long term exposure: -

Skin Contact:

Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin. Other symptoms may also become evident, but all should disappear once exposure has ceased.

Long term expsoure: -

Eye Contact:

Short term exposure: Available data shows that this product is not harmful. However product is an eye irritant. Symptoms may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent damage.

Long term expsoure: -

Ingestion:

Short term exposure: Available data shows that this product is harmful. Symptoms of poisoning observed in laboratory animals include pupil dilation, vomiting, convulsions and/or tremors, and coma.. This product is unlikely to cause any irritation problems in the short or long term.

Long term expsoure: -

Carcinogen Status:

SWA: No significant ingredient is classified as carcinogenic by SWA

NTP: No significant ingredient is classified as carcinogenic by NTP.

IARC: No significant ingredient is classified as carcinogenic by IARC.

section 3 - Composition/ Information on Ingredients: 
Ingredients CAS No Conc,% TWA (mg/m3) STEL (mg/m3)
Abamectin 71751-41-2 1.8 not set not set
N-Methyl-2-pyrrolidone 872-50-4 28 103 309
Liquid hydrocarbon secret 5.8 not set not set
Other non hazardous ingredients secret to 100 not set not set

 

This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible.

The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.

section 4 - First Aid Measures: 

General Information:

You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call.

Inhalation: If inhalation occurs, contact a Poisons Information Centre. Hospital treatment is likely to be needed. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.

Skin Contact: Quickly and gently, blot or brush away excess chemical. Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 20 minutes or until chemical is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g. watchbands and belts). If irritation persists, repeat flushing and obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or discard. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.

Eye Contact: Quickly and gently blot or brush away product. Immediately flush the contaminated eye(s) with lukewarm, gently flowing water until the product is removed or until a few minutes after irritation has ceased, while holding the eyelid(s) open. Take care not to rinse contaminated water into the unaffected eye or onto the face. Obtain medical advice if irritation becomes painful or lasts more than a few minutes.

Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information Centre, or call a doctor

section 5 - Fire Fighting Measures: 

Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption may occur upon application of direct water stream on hot liquids. Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures. .

Extinguishing Media: Water fog or fine spray is the preferred medium for large fires. Try to contain spills, minimise spillage entering drains or water courses.

Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. There is little danger of a violent reaction or explosion if significant quantities of this product are involved in a fire. Recommended personal protective equipment is liquid-tight chemical protective clothing and breathing apparatus.

Flash point: Not flammable.
Upper Flammability Limit: No data
Lower Flammability Limit: No data
Autoignition temperature:  No data
Flammability Class:  C1
section 6 - Accidental Release Measures: 

Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate the spill area and deny entry to unnecessary and unprotected personnel. Wear full protective chemically resistant clothing including face mask, face shield, gauntlets and self contained breathing apparatus. See above under Personal Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective clothing include rubber, PVC. Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Because of the toxicity of this product, special personal care should be taken in any cleanup operation. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.

section 7 - Handling and Storage: 

Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10.

Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage of this class of poison. Store in a cool, well ventilated area. Check containers periodically for leaks. Containers should be kept closed in order to minimise contamination. Make sure that the product does not come into contact with substances listed under "Materials to avoid" in Section 10. If you keep more than 1000kg or 1000L of Toxic Substances of Packaging Group III, you will require a license to do so. If you have any doubts, we suggest you contact your licensing authority in order to clarify your obligations. Check packaging - there may be further storage instructions on the label.

section 8 - Exposure Controls and Personal Protection: 

The following Australian Standards will provide general advice regarding safety clothing and equipment: Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501 set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.

SWA Exposure Limits TWA (mg/m3) STEL (mg/m3)
N-Methyl-2-pyrrolidone 103 309

The ADI for Abamectin is set at 0.0005mg/kg/day. The corresponding NOEL is set at 0.5mg/kg/day. ADI means Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Sept 2011.

Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that dusts are minimised.

Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where this product is being used.

Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin areas are covered. See below for suitable material types.

Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC.

Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being used.

section 9 - Physical and Chemical Properties: 


 

Physical Description & colour: Clear, colourless liquid.
Odour: Characteristic odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No specific data. Expected to be low at 100°C.
Vapour Pressure: No data
Vapour Density: No data
Specific Gravity: 1.01
Water Solubility: Soluble
pH: No data
Volatility: No data
Odour Threshold: No data
Evaporation Rate: No data
Coeff Oil/water distribution: No data
Autoignition temp: No data
section 10 - Stability and Reactivity: 

Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties.

Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Containers should be kept dry. Keep isolated from combustible materials.

Incompatibilities: strong oxidising agents.

Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.

Polymerisation: This product is unlikely to undergo polymerisation processes.

section 11 - Toxicological Information: 

Toxicity:

Acute toxicity: Abamectin is highly toxic to insects and may be highly toxic to mammals as well. Emulsifiable concentrate formulations may cause slight to moderate eye irritation and mild skin irritation. Symptoms of poisoning observed in laboratory animals include pupil dilation, vomiting, convulsions and/or tremors, and coma. Abamectin acts on insects by interfering with the nervous system. At very high doses, it can affect mammals, causing symptoms of nervous system depression such as incoordination, tremors, lethargy, excitation, and pupil dilation. Very high doses have caused death from respiratory failure. Abamectin is not readily absorbed through skin. Tests with monkeys show that less than 1% of dermally applied abamectin was absorbed into the bloodstream through the skin. Abamectin does not cause allergic skin reactions. The oral LD50 for abamectin in rats is 10 mg/kg, and in mice ranges from 14 mg/kg to greater than 80 mg/kg. The dermal LD50 for technical abamectin in rats and rabbits is greater than 330 mg/kg.

Chronic toxicity:  In a 1-year study with dogs given oral doses of abamectin, dogs at the 0.5 and 1 mg/kg/day doses exhibited pupil dilation, weight loss, lethargy, tremors, and recumbency. Similar results were seen in a 2-year study with rats fed 0.75, 1.5, or 2 mg/kg/day. Rats at all the dosage levels exhibited body weight gains significantly higher than the controls. A few individuals in the high dose group exhibited tremors. When mice were fed 8 mg/kg/day for 94 weeks, the males developed dermatitis and changes in blood formation in the spleen, while females exhibited tremors and weight loss.

Reproductive effects: Rats given 0.40 mg/kg/day of abamectin had increased stillbirths, decreased pup viability, decreased lactation, and decreased pup weights. These data suggest that abamectin may have the potential to cause reproductive effects at high enough doses.

Teratogenic effects: Abamectin produced cleft palate in the offspring of treated mice and rabbits, but only at doses that were also toxic to the mothers. There were no birth defects in the offspring of rats given up to 1 mg/kg/day. Abamectin is unlikely to cause teratogenic effects except at doses toxic to the mother.

Mutagenic effects:  Abamectin does not appear to be mutagenic. Mutagenicity tests in live rats and mice were negative. Abamectin was shown to be nonmutagenic in the Ames test.

Carcinogenic effects:  Abamectin is not carcinogenic in rats or mice. The rats were fed dietary doses of up to 2 mg/kg/day for 24 months, and the mice were up to 8 mg/kg/day for 22 months. These represent the maximum tolerated doses.

Organ toxicity: Animal studies indicate that abamectin may affect the nervous system.

Fate in humans and animals:  Tests with laboratory animals show that ingested avermectin B1a is not readily absorbed into the bloodstream by mammals and that it is rapidly eliminated from the body within 2 days via the faeces. Rats given single oral doses of avermectin B1a excreted 69 to 82% of the dose unchanged in the faeces. The average half-life of avermectin B1a in rat tissue is 1.2 days. Lactating goats given daily oral doses for 10 days excreted 89% of the administered avermectin, mainly in the faeces. Less than 1% was recovered in the urine.

section 12 - Ecological Information: 

This product is biodegradable. It will not accumulate in the soil or water or cause long term problems

Effects on birds: Abamectin is practically nontoxic to birds. The LD50 for abamectin in bobwhite quail is >2000 mg/kg. The dietary LC50 is 3102 ppm in bobwhite quail. There were no adverse effects on reproduction when mallard ducks were fed dietary doses of 3, 6, or 12 ppm for 18 weeks.

Effects on aquatic organisms: Abamectin is highly toxic to fish and extremely toxic to aquatic invertebrates. Its LC50 (96-hour) is 0.003 mg/L in rainbow trout, 0.0096 mg/L in bluegill sunfish, 0.015 mg/L in sheepshead minnows, 0.024 mg/L in channel catfish, and 0.042 mg/L in carp. Its 48-hour LC50 in Daphnia magna, a small freshwater crustacean, is 0.003 mg/L. The 96-hour LC50 for abamectin is 0.0016 mg/L in pink shrimp, 430 mg/L in eastern oysters, and 153 mg/L in blue crab. While highly toxic to aquatic organisms, actual concentrations of abamectin in surface waters adjacent to treated areas are expected to be low. Abamectin did not bioaccumulate in bluegill sunfish exposed to 0.099 μg/L for 28 days in a flow-through tank. The levels in fish were from 52 to 69 times the ambient water concentration, indicating that abamectin does not accumulate or persist in fish.

Effects on other organisms: Abamectin is highly toxic to bees, with a 24-hour contact LC50 of 0.002 μg/bee and an oral LD50 of 0.009 μg/bee

Environmental Fate:

Breakdown in soil and groundwater: Abamectin is rapidly degraded in soil. At the soil surface, it is subject to rapid photodegradation, with half-lives of 8 hours to 1 day reported. When applied to the soil surface and not shaded, its soil half-life is about 1 week. Under dark, aerobic conditions, the soil half-life was 2 weeks to 2 months. Loss of abamectin from soils is thought to be due to microbial degradation. The rate of degradation was significantly decreased under anaerobic conditions. Because abamectin is nearly insoluble in water and has a strong tendency to bind to soil particles, it is immobile in soil and unlikely to leach or contaminate groundwater. Compounds produced by the degradation of abamectin are also immobile and unlikely to contaminate groundwater.

Breakdown in water: Abamectin is rapidly degraded in water. After initial distribution, its half-life in artificial pond water was 4 days. Its half-life in pond sediment was 2 to 4 weeks. It undergoes rapid photodegradation, with a half-life of 12 hours in water. When tested at pH levels common to surface and groundwater (pH 5, 7, and 9), abamectin did not hydrolyze.

Breakdown in vegetation: Plants do not absorb abamectin from the soil. Abamectin is subject to rapid degradation when present as a thin film, as on treated leaf surfaces. Under laboratory conditions and in the presence of light, its half-life as a thin film was 4 to 6 hours.

section 13 - Disposal Considerations: 

Disposal: Instructions concerning the disposal of this product and its containers are given on the registered label. These should be carefully followed. Special help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.

section 14 - Transport Information: 

ADG Code: 2902, PESTICIDE, LIQUID, TOXIC, N.O.S.

Hazchem Code: 2X

Special Provisions: 61, 223, 274

Limited quantities: ADG 7 specifies a Limited Quantity value of 5 L for this class of product.

Dangerous Goods Class: Class 6.1, Toxic Substances.

Packaging Group: III

Packaging Method: P001, IBC03, LP01

Class 6 Toxic Substances shall not be loaded in the same vehicle or packed in the same freight container with Classes 1 (Explosives), 3 (Flammable Liquids where the Flammable Liquid is nitromethane), 5.1 (Oxidising Agents where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides where the Toxic Substances are Fire Risk Substances), 8 (Corrosive Substances where the Toxic Substances are cyanides and the Corrosives are acids), Foodstuffs and foodstuff empties. They may however be loaded in the same vehicle or packed in the same freight container with Classes, 2.1 (Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Toxic Gases), 3 (Flammable liquids, except where the flammable liquid is nitromethane), 4.1 (Flammable Solids), 4.2 (Spontaneously Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1 (Oxidising Agents except where the Toxic Substances are Fire Risk Substances), 5.2 (Organic Peroxides except where the Toxic Substances are Fire Risk Substances), 7 (Radioactive Substances), 8 (Corrosive Substances except where the Toxic Substances are cyanides and the Corrosives are acids), 9 (Miscellaneous Dangerous Goods)

section 15 - Regulatory Information: 

AICS: All of the significant ingredients in this product are compliant with NICNAS regulations.

section 16 - Other Information: 

This MSDS contains only safety-related information. For other data see product literature.

Acronyms:  
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail, 7th Edition
AICS Australian Inventory of Chemical Substances
SWA Safe Work Australia, formerly ASCC and NOHSC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSMP Standard for the Uniform Scheduling of Medicines & Poisons
UN Number United Nations Number

 

Contact Points:

Call Adama on (02)9431 7800 and ask for the technical manager.   Fax: (02)9431 7700

 

Police and Fire Brigade:  Dial 000
Emergency contact:  1800 024 973 (24 hours)

 

If ineffective:

Dial Poisons Information Centre (13 1126 from anywhere in Australia)

The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining its appropriateness for a particular purpose. Adama Australia Pty Ltd makes no representation as to the accuracy or comprehensiveness of the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data Sheet.

Please read all labels carefully before using product.

This MSDS is prepared in accord with the SWA document “National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition [NOHSC:2011(2003)] Copyright © Kilford & Kilford Pty Ltd, August, 2012. http://www.kilford.com.au/ Phone (02)9251 4532